Inloggen Gratis proberen

Follow us

Welkome bij Bookboon

Om onze services te kunnen leveren, gebruiken we een reeks essentiële cookies.

Zie cookiegegevens
Categorieën Zakelijk
Gratis leerboek

Chemical Thermodynamics

bij Leo Lue
(37 Beoordelingen)
1 review
90
Taal:  English
This study guide deals with the application of thermodynamics to the description of the properties of materials.
Download gratis tekstboeken als PDF of lees ze online. Minder dan 15% advertenties.
Het zakelijk abonnement is gratis voor de eerste 30 dagen, daarna$5.99/maand
Beschrijving
Inhoud
Beoordelingen

This study guide deals with the application of thermodynamics to the description of the properties of materials. It covers the qualitative behavior of single and multicomponent mixtures, including vapor-liquid, liquid-liquid, and solid-liquid phase equilibria. It also explains the use of activity coefficient models and equations of state for the quantitative prediction of phase behavior and chemical reaction equilibria. The guide assumes a prior basic understanding of first and second laws of thermodynamics and multivariate calculus.

  1. Introduction
    1. Basic concepts
    2. Brief review of thermodynamics
    3. The fundamental equation of thermodynamics
    4. The calculus of thermodynamics
    5. Open systems
    6. Legendre transforms and free energies
  2. Single component systems
    1. General phase behavior
    2. Conditions for phase equilibrium
    3. The Clapeyron equation
  3. Multicomponent systems
    1. Thermodynamics of multicomponent systems
    2. Binary mixtures
    3. Ternary mixtures
  4. The ideal solution model
    1. Definition of the ideal solution model
    2. Derivation of Raoult’s law
  5. Partial molar properties
    1. Definition
    2. Relationship between total properties and partial molar properties
    3. Properties changes on mixing
    4. Graphical representation for binary systems
  6. Nonideal solutions
    1. Deviations from Raoult’s law and the activity coefficient
    2. Modified Raoult’s law
    3. Empirical activity coefficient models
    4. The Gibbs-Duhem equation
    5. Azeotropic systems
  7. Stability
    1. Introduction
    2. Liquid-liquid equilibrium
  8. Solid-liquid equilibrium
    1. Introduction
    2. Phase behavior
    3. Conditions for equilibrium
  9. Gas solubility and Henry’s law
    1. Henry’s law
    2. Activity coefficients
  10. Equations of state
    1. The principle of corresponding states
    2. The van der Waals equation and cubic equations of state
    3. Equations of state for mixtures
  11. Thermodynamics from equations of state
    1. The residual Helmholtz free energy
    2. Fugacity
    3. Vapor-liquid equilibrium with a non-ideal vapor phase
  12. Chemical reaction equilibria
    1. Conditions for equilibrium
    2. The phase rule for chemically reacting systems
    3. Gas phase reactions
    4. The standard Gibbs free energy of formation
    5. The influence of temperature
    6. Liquid phase reactions
a chem. eng. student
This book explains hard concepts in a very clear way. Very good!
More reviews
Schrijf een beoordeling
Over de auteur

Leo Lue

Ontdek de auteur
Gerelateerd materiaal